Note that a catalyst decreases the activation energy for both the forward and the reverse reactions and hence accelerates both the forward and the reverse reactions.Formula: C8H6N2, you can also check out more blogs about254-60-4
Chemistry is an experimental science, and the best way to enjoy it and learn about it is performing experiments. Formula: C8H6N2. Introducing a new discovery about 254-60-4, Name is 1,8-Diazanaphthalene
The addition of 1,8-naphthyridine (naph) to a solution of at room temperature affords the octahedral complex ClO4 (1).This complex can also be obtained when naph is added to a solution of .When naph is reacted with at -80 deg C and with 1:1 molar ratio, ClO4 (3) is obtained.This complex changes into (1) at temperatures sbove 0 deg C.The crystal structure of ClO4 (monoclinic, space group P21/a, a = 16.006(3) Angstroem, b = 12.024(2) Angstroem, c = 13.004(2) Angstroem, beta = 109.85(2) deg, Z = 4) shows that the manganese atom displays a slightly distorted octahedral coordination being linked to three facial carbonyl ligands, to two nitrogen atoms of a bidentate 1,8-naphthyridine (eta2-naph) and to another nitrogen atom of a monodentate 1,8-naphthyridine (eta1-naph).A detailed variable temperature 1H NMR study shows this structure persist in solution at low temperature.At higher temperature the complex is fluxional and there is a rapid exchange of the coordination modes of the two naph ligands: the bidentate becomes monodentate and the monodentate bidentate.The mechanism is intramolecular, the rate-limiting step being the opening of the four-membered ring formed by the metal and the eta2-naph.
Note that a catalyst decreases the activation energy for both the forward and the reverse reactions and hence accelerates both the forward and the reverse reactions.Formula: C8H6N2, you can also check out more blogs about254-60-4
Reference£º
1,60-Naphthyridine – Wikipedia,
1,8-Naphthyridine | C8H6N54 – PubChem