A catalyst don’t appear in the overall stoichiometry of the reaction it catalyzes, but it must appear in at least one of the elementary reactions in the mechanism for the catalyzed reaction. 40138-16-7, Name is (2-Formylphenyl)boronic acid, molecular formula is C7H7BO3. In an article, author is Kounalis, Errikos,once mentioned of 40138-16-7, Recommanded Product: 40138-16-7.
Tuning the Bonding of a mu-Mesityl Ligand on Dicopper(I) through a Proton-Responsive Expanded PNNP Pincer Ligand
We report the synthesis and characterization of a series of cationic, neutral, and anionic dicopper(I) complexes featuring a p-mesityl ligand and a naphthyridine-derived PNNP expanded pincer ligand. Structural characterization showed that the protonation state of the dinucleating ligand has a pronounced effect on the bending and tilting of the mu-mesityl ligand. DFT calculations indicate that the varying orientations of the mu-mesityl ligand are inherent due to changes in electronic structure rather than crystal-packing effects. NBO analysis reveals how the interactions that contribute to the three-center two-electron bond between the mu-mesityl ligand and the dicopper core change for the various degrees of observed bending and tilting.
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Reference:
1,8-Naphthyridine – Wikipedia,
,1,8-Naphthyridine | C8H6N2 – PubChem