Extracurricular laboratory: Discover of 13822-56-5

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Let¡¯s face it, organic chemistry can seem difficult to learn. Especially from a beginner¡¯s point of view. Like 13822-56-5, Name is 3-(Trimethoxysilyl)propan-1-amine. In a document, author is Ghatak, Tapas, introducing its new discovery. Product Details of 13822-56-5.

Cyclometalated Ir-Sn Construct for Cyanosilylation

Two cyclometalated compounds [(IrCl)-Cl-III{(2-biphenylene-1,8-naphthyridine-kappa C,N}(eta (5)-pentamethylcyclopentadienyl)] (1) and [(IrCl)-Cl-III{(2-(2-N-Methyl-pyrrolyl-1,8-naphthyridine-kappa C,N}(eta (5)-pentamethylcyclopentadienyl)] (2) containing naphthyridine based ligands have been synthesized in high yield. Insertion of SnCl2 to a terminal Ir-Cl bond of 1 affords the mixed Ir-SnCl3 compound [(IrSnCl3)-Sn-III{(2-biphenylene-1,8-naphthyridine-kappa C,N}(eta (5)-pentamethylcyclopentadienyl)] (3). The heterobimetallic compound 3 is shown to be an excellent catalyst for a variety of cyanosilylation reactions. A cooperative mechanism has been proposed which involves the simultaneous activation of aldehyde and cyanide precursor by Sn and unbound naphthyridine nitrogen.

I hope this article can help some friends in scientific research. I am very proud of our efforts over the past few months and hope to 13822-56-5 help many people in the next few years. Product Details of 13822-56-5.

Reference:
1,8-Naphthyridine – Wikipedia,
,1,8-Naphthyridine | C8H6N2 – PubChem