Extracurricular laboratory: Discover of 4-(Trifluoromethyl)acetophenone

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A catalyst don’t appear in the overall stoichiometry of the reaction it catalyzes, but it must appear in at least one of the elementary reactions in the mechanism for the catalyzed reaction. 709-63-7, Name is 4-(Trifluoromethyl)acetophenone, molecular formula is C9H7F3O. In an article, author is Sarbajna, Abir,once mentioned of 709-63-7, Category: naphthyridines.

Catalytic Conversion of Alcohols to Carboxylic Acid Salts and Hydrogen with Alkaline Water

A [RuH(CO)(py-NP)(PPh3)(2)]Cl (1) catalyst is found to be effective for catalytic transformation of primary alcohols, including amino alcohols, to the corresponding carboxylic acid salts and two molecules of hydrogen with alkaline water. The reaction proceeds via acceptorless dehydrogenation of alcohol, followed by a fast hydroxide/water attack to the metal-bound aldehyde. A pyridyl-type nitrogen in the ligand architecture seems to accelerate the reaction.

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Reference:
1,8-Naphthyridine – Wikipedia,
,1,8-Naphthyridine | C8H6N2 – PubChem