Related Products of 179324-87-9, Enzymes are biological catalysts that produce large increases in reaction rates and tend to be specific for certain reactants and products. 179324-87-9, Name is (R)-BoroLeu-(+)-Pinanediol trifluoroacetate, SMILES is CC1(C)[C@@]([H])(C2)C[C@]3([H])[C@](OB([C@H](CC(C)C)N)O3)(C)[C@]12[H].O=C(O)C(F)(F)F, belongs to naphthyridine compound. In a article, author is Chahal, Mandeep K., introduce new discover of the category.
1,8-Naphthyridinic fluorescent ‘turn-on’ and ‘turn-off’ chemosensors for detection of F- and Hg2+ ions mimicking INHIBIT molecular logic behaviour
Two new receptors viz. 2-bromoacetamido-5,7-dimethyl-1,8-naphthyridine (1a) and 2-chloroacetamido-5,7-dimethyl-1,8-naphthyridine (1b) containing 1,8-naphthyridine as fluorophore unit have been designed and synthesised. These receptors exhibited very high selectivity for F- ions among the various anions tested such as H2PO4-, OAc-, Cl-, Br-, I-, HSO4-, PF6-, ClO4-, BF4- and NO3- owing to anion-induced deprotonation of the amide NH by F- ions. Among the various cations tested (Na+, Ag+, Co2+, Ni2+, Cu2+, Zn2+, Cd2+, Hg2+, Pb2+ and Mn3+), 1a exhibited selective detection of Hg2+ ions by binding with N1 and N8 atoms of the naphthyridine moiety. Receptor 1a has been explored as a dual-ion detector for F- and Hg2+ ions in two contrasting modes (fluorescence ‘turn-on’ and ‘turn-off’) which is supported by spectroscopic and lifetime measurements. 1a exhibited lower detection limits for F- (0.4 ppm) and Hg2+ (2.4 ppm) ions. These receptors were recovered from anionic species of 1a formed after addition of F- ions by treating with protic solvents such as CH3OH. The mode of binding was also confirmed by spectroscopic and DFT studies. The chemical inputs of F- and Hg2+ ions generate an output which satisfies the condition of two-input INHIBIT logic operators.
Related Products of 179324-87-9, Consequently, the presence of a catalyst will permit a system to reach equilibrium more quickly, but it has no effect on the position of the equilibrium as reflected in the value of its equilibrium constant.I hope my blog about 179324-87-9 is helpful to your research.
Reference:
1,8-Naphthyridine – Wikipedia,
,1,8-Naphthyridine | C8H6N2 – PubChem