New Advances in Chemical Research, April 2021.The transformation of simple hydrocarbons into more complex and valuable products via catalytic C¨CH bond functionalisation has revolutionised modern synthetic chemistry. 40138-16-7, Name is (2-Formylphenyl)boronic acid, SMILES is O=CC1=CC=CC=C1B(O)O, belongs to naphthyridine compound. In a document, author is Oyama, Dai, introduce the new discover, Computed Properties of https://www.ambeed.com/products/40138-16-7.html.
The asymmetric unit of the title compound, [Ru(C13H9N3)(C15H11N3)(H2O)](PF6)(2)center dot 1.5C(3)H(6)O, consists of two crystallographically independent RuII complexes. Each complex is approximately octahedral with the RuII atom bound by an N,N’-coordinated 2-(2-pyridyl)-1,8-naphthyridine (pynp) ligand, a meridional 2,2′:6′,2”-terpyridine (tpy) ligand and one aqua ligand. The tpy ligand is coordinated in a planar tridentate fashion with the central N atom closest to the RuII atom. The aqua ligand is trans to the pyridine N atom of pynp. The long Ru-O distances [2.150 (5) and 2.138 (5) A] are typical for aqua ligands in polypyridyl ruthenium complexes. In the crystal, both intramolecular O-H…N and intermolecular O-H…O hydrogen bonds are observed.
Therefore, this conceptually novel strategy might open impressive avenues to establish green and sustainable chemistry platforms. If you like, you can also browse other articles about this kind. Thanks for taking the time to read the blog about 40138-16-7, Computed Properties of https://www.ambeed.com/products/40138-16-7.html.
Reference:
1,8-Naphthyridine – Wikipedia,
,1,8-Naphthyridine | C8H6N2 – PubChem