New Advances in Chemical Research in 2021. Chemo-enzymatic cascade processes are invaluable due to their ability to rapidly construct high-value products from available feedstock chemicals in a one-pot relay manner. 13922-41-3, Name is Naphthalen-1-ylboronic acid, molecular formula is , belongs to naphthyridine compound. In a document, author is Chen, Chen, Application In Synthesis of Naphthalen-1-ylboronic acid.
Two new copper(I) complexes [Cu(L-1)(2))PF6 (L-1 = 4-diphenylphosphino-1,5-naphthyridine, 1) and]Cu(L-2)(2)] PF6 (L-2 = 4-diphenylphosphino-8-methyl-1,5-naphthyridine, 2), have been prepared and characterized. In each of them, the coordinate geometry of Cu atom is a distorted square planar configuration with bond distances and angles in the normal range. Moreover, compound 2 features one-dimensional zigzag chains which are cross-linked by the metal complex cations and PF6- anions through hydrogen bonding interactions. The HOMO-LUMO energy gaps of 1-2 estimated by the cyclic voltammetry (CV) show values in the order of 1 > 2. Both 1 and 2 show low-energy bands ranging from 360 to 430 nm and available florescence in the solid state at room temperature with lambda(max) = 532-541 nm. The UV-vis absorption spectra of 1-2 show obvious red-shifts compared with those of the corresponding quinoline containing Cu(I) complexes [Cu(QN)(2)]PF6 (QN = 8-diphenylphosphino quinoline), exhibiting the HOMO-LUMO energy gaps of 1-2 should be narrower than that of [Cu(QN)(2)]PF6. (C) 2011 Elsevier B.V. All rights reserved.
These may comprise an expansion of the substrate scope from aromatic and heteroaromatic compounds to other hydrocarbons. If you like, you can also browse other articles about this kind. Thanks for taking the time to read the blog about 13922-41-3, Application In Synthesis of Naphthalen-1-ylboronic acid.
Reference:
1,8-Naphthyridine – Wikipedia,
,1,8-Naphthyridine | C8H6N2 – PubChem