New Advances in Chemical Research in 2021. In an article, author is Ismayilov, Rayyat Huseyn, once mentioned the application of 5959-52-4, Name is 3-Amino-2-naphthoic acid, molecular formula is C11H9NO2, molecular weight is 187.1947, category is naphthyridine. Now introduce a scientific discovery about this category, Product Details of 5959-52-4.
Through a pyrimidine and naphthyridine-containing triamine ligand, N-2-(pyrimidin-2-yl)-N-7-(2-(pyrimidin-2-ylamino)-1,8-naphthyridin-7-yl)-1,8-naphthyridine-2,7-diamine (H3N9-2pm), defective metal string complex [Ni-8.33(N-9-2pm)(4)(NCS)(2)](PF6)(2) (1) was successfully synthesized and structurally characterized. The complex consists of a linear metal chain and four deprotonated supporting ligands which are helically wrapped around the metal score. X-Ray crystallographic studies revealed that the complex (1) crystallizes in space group P2(1)/c of the monoclinic system. The small J value (J = -2.90 cm(-1)) suggests quite a weak magnetic interaction throughout the molecule of complex (1). The weak magnetic interaction in the defective complex indicates that the spin exchange in metal string occurs through the metal core rather than the bridging ligands. The electrochemical study on complex 1 shows abundant redox properties and facility to the reduction in its cyclic voltammogram by displaying three reversible redox couples at E-1/2 = – 0.35, – 0.69 and – 0.88 V. (C) 2019 Elsevier B.V. All rights reserved.
The prevalence of solvent effects in heterogeneous catalysis in condensed media has motivated developing quantitative kinetic, their interactions with reaction intermediates and transition states. I hope my blog about 5959-52-4 is helpful to your research. Product Details of 5959-52-4.
Reference:
1,8-Naphthyridine – Wikipedia,
,1,8-Naphthyridine | C8H6N2 – PubChem