New Advances in Chemical Research, April 2021.The transformation of simple hydrocarbons into more complex and valuable products via catalytic C–H bond functionalisation has revolutionised modern synthetic chemistry. 16415-12-6, Name is Hexadecyltrimethoxysilane, SMILES is CO[Si](OC)(CCCCCCCCCCCCCCCC)OC, belongs to naphthyridine compound. In a document, author is Wu, Yun-Ying, introduce the new discover, Application In Synthesis of Hexadecyltrimethoxysilane.
Two novel naphthyridine-BF2 compounds with an amide-containing di-2-picolylamine (DPA) receptor, namely 4 and 5, were synthesized and structurally characterized by various spectroscopic techniques and X-ray diffraction crystallography. The crystal structures of both mononuclear 4 and dinuclear 5 possessed a N,O-chelated naphthyridine-BF2 core, and the second BF2 unit in 5 was ligated to a basic amido N-atom together with a tertiary amine in the DPA part. The spectroscopic properties of 4 and 5 were investigated in various solvents and the difference between them was rationalized by the intramolecular charge transfer (ICT) and photo-induced electron transfer (PET) mechanism. Cyclic voltammetry measurements and theoretical calculations were carried out, and the results were in agreement with their spectral data. (C) 2013 Elsevier B.V. All rights reserved.
The result showed that such a combination of chemo- and biocatalysis improved the catalytic yield more than two times compared with that of sole metal catalysis.Welcome to check out more blogs about 16415-12-6, in my other articles. Application In Synthesis of Hexadecyltrimethoxysilane.
Reference:
1,8-Naphthyridine – Wikipedia,
,1,8-Naphthyridine | C8H6N2 – PubChem