Sakamoto, Takao’s team published research in Chemical & Pharmaceutical Bulletin in 1985-02-28 | CAS: 67988-50-5

Chemical & Pharmaceutical Bulletin published new progress about Cross-coupling reaction. 67988-50-5 belongs to class naphthyridine, name is 2,7-Naphthyridin-1(2H)-one, and the molecular formula is C8H6N2O, Product Details of C8H6N2O.

Sakamoto, Takao published the artcileCondensed heteroaromatic ring systems. III. Synthesis of naphthyridine derivatives by cyclization of ethynylpyridinecarboxamides, Product Details of C8H6N2O, the main research area is cyclization ethynylpyridinecarboxamide; naphthyridinone; coupling palladium halopyridine acetylene.

Naphthyridinones I and II (R = H, R1R2, R2R1 = CONHCH:CH; R=Me, R1R2, R2R1 = CONHCPh:CH) were synthesized by the ring closure of pyridinecarboxamides I and II [R = H, R1(R2) = CONH2, R2(R1) = CH2CH(OMe)2; R = Me, R1(R2) = CONH2, R2(R1) = CCPh]. The starting pyridines I [R = H, R1(R2) = cyano, R2(R1)=CCSiMe3; R =Me, R2(R1) = CCPh] and II [R = H, R1(R2) = cyano, R2(R1) = CCSiMe3; R= Me, R1 = CONH2, R2 = CCPh; R = Me, R1 = CCPh, R2 = CO2Et] were easily synthesized by the Pd-catalyzed cross-coupling of halopyridines with PhCCH or Me3SiCCH.

Chemical & Pharmaceutical Bulletin published new progress about Cross-coupling reaction. 67988-50-5 belongs to class naphthyridine, name is 2,7-Naphthyridin-1(2H)-one, and the molecular formula is C8H6N2O, Product Details of C8H6N2O.

Referemce:
1,8-Naphthyridine – Wikipedia,
1,8-Naphthyridine | C8H6N2 – PubChem