Children learn through play, and they learn more than adults might expect. Science experiments are a great way to spark their curiosity, Safety of (R)-BoroLeu-(+)-Pinanediol trifluoroacetate179324-87-9, Name is (R)-BoroLeu-(+)-Pinanediol trifluoroacetate, SMILES is CC1(C)[C@@]([H])(C2)C[C@]3([H])[C@](OB([C@H](CC(C)C)N)O3)(C)[C@]12[H].O=C(O)C(F)(F)F, belongs to naphthyridine compound. In a article, author is Maity, Arnab K., introduce new discover of the category.
Carbene Formation and Transfer at a Dinickel Active Site
The synthesis and reactivity of a dinickel bridging carbene is described. The previously reported [i-PrND]Ni-2(C6H6) complex (NDI = naphthyridine-diimine) reacts with Ph2CN2 to generate a metastable diazoalkane adduct, which eliminates N-2 at 60 degrees C to yield a paramagnetic Ni-2(mu-CPh2) complex. The Ni-2(mu-CPh2) complex undergoes carbene transfer to t-BuNC via an initial isonitrile adduct, which upon heating releases free t-BuNCCPh2. On the basis of this sequence of stoichiometric reactions, a catalytic carbene transfer reaction is demonstrated.
Note that a catalyst decreases the activation energy for both the forward and the reverse reactions and hence accelerates both the forward and the reverse reactions. you can also check out more blogs about 179324-87-9. Safety of (R)-BoroLeu-(+)-Pinanediol trifluoroacetate.
Reference:
1,8-Naphthyridine – Wikipedia,
,1,8-Naphthyridine | C8H6N2 – PubChem