You could be based in a university, combining chemical research with teaching; in a pharmaceutical company, working on developing and trialing new drugs; helping to ensure national healthcare provision keeps pace with new discoveries. , Name: (R)-BoroLeu-(+)-Pinanediol trifluoroacetate, 179324-87-9, Name is (R)-BoroLeu-(+)-Pinanediol trifluoroacetate, molecular formula is C17H29BF3NO4, belongs to naphthyridine compound. In a document, author is Maity, Arnab K., introduce the new discover.
The synthesis and reactivity of a dinickel bridging carbene is described. The previously reported [i-PrND]Ni-2(C6H6) complex (NDI = naphthyridine-diimine) reacts with Ph2CN2 to generate a metastable diazoalkane adduct, which eliminates N-2 at 60 degrees C to yield a paramagnetic Ni-2(mu-CPh2) complex. The Ni-2(mu-CPh2) complex undergoes carbene transfer to t-BuNC via an initial isonitrile adduct, which upon heating releases free t-BuNCCPh2. On the basis of this sequence of stoichiometric reactions, a catalytic carbene transfer reaction is demonstrated.
Catalysts are substances that increase the reaction rate of a chemical reaction without being consumed in the process. Welcome to check out more blogs about 179324-87-9, in my other articles. Name: (R)-BoroLeu-(+)-Pinanediol trifluoroacetate.
Reference:
1,8-Naphthyridine – Wikipedia,
,1,8-Naphthyridine | C8H6N2 – PubChem