Bruce, Michael I.’s team published research in Applied Organometallic Chemistry in 16 | CAS: 18512-55-5

Applied Organometallic Chemistry published new progress about 18512-55-5. 18512-55-5 belongs to naphthyridine, auxiliary class Alkynyl,Anthracene, name is 9,10-Diethynylanthracene, and the molecular formula is C18H10, SDS of cas: 18512-55-5.

Bruce, Michael I. published the artcileSome platinum(II) complexes derived from aromatic alkynes, SDS of cas: 18512-55-5, the publication is Applied Organometallic Chemistry (2002), 16(10), 559-568, database is CAplus.

Several trans-platinum(II) complexes, of the type {trans-RPt(PBu3)2}-Q-{trans-Pt(PR3)2R}, where R and Q are groups derived from a series of aromatic alkynes and diynes, were prepared and characterized. Platination of trans-[(4-R1-2,5-R22-C6H2CC)2PtL2] (L = PBu3 or PTol3; R2 = H or OMe; R1 = HCC) with trans-L2PtCl2 afforded trans-[ClPtL2(CCC6H2-2,5-R22-4-CC)PtL2(CCC6H2-2,5-R22-4-CC)PtL2Cl], which were alkynylated by 4-(R3CC)(C6H2-2,5-R22)CCH (R3 = H, Ph) to give trinuclear bis-alkynylated platinum rod-like complexes. The same reaction of 1,4-diethynylarenes with subsequent alkynylation gave analogous binuclear complexes. Similar reaction led to trinuclear [trans-PtCl(PBu3)(CCC6H4-4-CCPh)]3[1,3,5-(CC)C6H3] complex. Coupling of trans-[(4-HCCC6H4CC)2Pt(PBu3)2] with 4-IC6H4X (X = I, OH, NH2, NO2) gave corresponding trans-[(4-XC6H4CCC6H4CC)2Pt(PBu3)2]. Spectroscopic data for these and other known related complexes are presented. A more precise structural study of trans-Pt(CCC6H4CCPh)2(PBu3)2 is reported.

Applied Organometallic Chemistry published new progress about 18512-55-5. 18512-55-5 belongs to naphthyridine, auxiliary class Alkynyl,Anthracene, name is 9,10-Diethynylanthracene, and the molecular formula is C18H10, SDS of cas: 18512-55-5.

Referemce:
https://en.wikipedia.org/wiki/1,8-Naphthyridine,
1,8-Naphthyridine | C8H6N2 – PubChem